Windows: Run this command
“”C:\Program Files\Mozilla Firefox\firefox.exe” -p -no-remote” and create new profile.

Create a new shortcut to Firefox and edit the target to “C:\Program Files\Mozilla Firefox\firefox.exe” -p “ProfileName”

 

For more detailed info go here: http://kb.mozillazine.org/Shortcut_to_a_specific_profile

 

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